Selective and effective adsorption of Hg(II) from aqueous solution over wide pH range by thiol functionalized...

In this study, a novel adsorbent thiol functionalized magnetic carbon nanotubes (CNTs-SH@Fe₃O₄) was synthesized to overcome somewhat existing difficulties during the Hg(II) adsorption process, including low efficiency and selectivity, narrow feasible pH range and difficult to separate and reuse. The Hg(II) adsorption performance of CNTs-SH@Fe₃O₄ was evaluated using batch experiment and its physiochemical properties were investigated by characterization techniques. The batch experiment results showed that the prepared CNTs-SH@Fe₃O₄ maintained high Hg(II) adsorption efficiency (>98%) over wide pH range from 3 to 11. The selective adsorption of Hg(II) by CNTs-SH@Fe₃O₄ was achieved with the coexistence of Cu(II), Mg(II) or Zn(II) ions, in which adsorbate matrix Hg(II) removal efficiency of 81.39%, 89.36% and 95.52% was obtained, respectively. CNTs-SH@Fe₃O₄ kept high Hg(II) removal efficiency (>80%) and good magnetic property (Ms value > 21 emg g^-1) after five cycles of adsorption/regeneration. The Hg(II) adsorption kinetics could be better described by pseudo-second-order kinetic model. Freundlich model showed higher correlation coefficient in adsorption isotherms study, and the calculated maximum adsorption capacity was 172.4 mg g^-1. Thermodynamic study suggested that the adsorption process was exothermic in nature. Surface adsorption, complex adsorption and reduction adsorption were all contributed to the removal of Hg(II) using CNTs-SH@Fe₃O₄.