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Destabilizing Pickering emulsions using fumed silica particles with different wettabilities
Christopher Griffith1, Hugh Daigle1
1Hildebrand Department of Petroleum and Geosystems Engineering, University of Texas at Austin, Austin, TX, USA.
Hydrophobic silica particles can destabilize Pickering emulsions. More hydrophobic particles are more effective at inducing coalescence, with highly hydrophobic particles achieving 85% oil coalescence.
Area of Science:
- Colloid and surface science
- Materials science
Background:
- Pickering emulsions are stabilized by colloidal particles at the oil/water interface, offering stability but posing challenges for destabilization.
- Hydrophobic particles are known to destabilize conventional surfactant-stabilized emulsions.
Purpose of the Study:
- To investigate the potential of hydrophobic colloidal particles for destabilizing Pickering emulsions.
- To explore the correlation between particle hydrophobicity and the ability to induce coalescence in Pickering emulsions.
Main Methods:
- A model oil-in-water Pickering emulsion was prepared using PEG-modified silica nanoparticles.
- Three types of fumed silica particles with varying hydrophobicity (hydrophilic, intermediate, hydrophobic) were added to assess their destabilization efficacy.
- Optical microscopy was employed to observe particle-emulsion interactions.
Main Results:
- A strong correlation was observed between fumed silica particle wettability and Pickering emulsion destabilization.
- Hydrophilic and intermediate hydrophobicity particles failed to induce coalescence due to wetting by the continuous phase.
- Hydrophobic fumed silica particles effectively coalesced the emulsion, achieving 85% oil coalescence at 0.05 wt% addition.
Conclusions:
- Sufficient particle hydrophobicity is crucial for destabilizing Pickering emulsions.
- Hydrophobic particles can dewet emulsion films and induce droplet coalescence, overcoming the steric barrier provided by stabilizing particles.
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