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Silane Cross-Linked Sulfonted Poly(Ether Ketone/Ether Benzimidazole)s for Fuel Cell Applications
Zilu Yao1, Mengbing Cui2, Zhenghui Zhang3
1CAS Key Laboratory of Soft Matter Chemistry, Collaborative Innovation Center of Chemistry for Energy Materials, School of Chemistry and Material Science, University of Science and Technology of China, Hefei 230026, China. yaozl@mail.ustc.edu.cn.
Abstract:
γ-(2,3-epoxypropoxy) propyltrimethoxysilane (KH-560) was incorporated in various proportions into side-chain-type sulfonated poly(ether ketone/ether benzimidazole) (SPEKEBI) as a crosslinker, to make membranes with high ion exchange capacities and excellent performance for direct methanol fuel cells (DMFCs). Systematical measurements including Fourier transform infrared (FT-IR), scanning electron microscopy-energy-dispersive and X-ray photoelectron spectroscopy (XPS) proved the complete disappearance of epoxy groups in KH-560 and the existence of Si in the membranes. The resulting membranes showed increased mechanical strength and thermal stability compared to the unmodified sulfonated poly(ether ketone/ether benzimidazole) membrane in appropriate doping amount. Meanwhile, the methanol permeability has decreased, leading to the increase of relative selectivities of SPEKEBI-x-SiO₂ membranes. Furthermore, the H₂/O₂ cell performance of SPEKEBI-2.5-SiO₂ membrane showed a much higher peak power density compared with the pure SPEKEBI memrbrane.
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Ethers can be prepared from organic compounds by various methods. Some of them are discussed below,
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02:28Structure and Nomenclature of Ethers
Ethers are organic compounds with an ether functional group which is characterized by an oxygen atom connected to two — identical or different — alkyl, aryl, or vinyl groups. The C–O–C linkage in dimethyl ether — the simplest ether — has an approximately tetrahedral bond angle of 110.3 degrees. The oxygen atom is sp3- hybridized, with the C–O distance being about 140 pm.
Classification of Ethers
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An ether molecule has a net dipole moment due to the polarity of C–O bonds. Subsequently, boiling points of ethers are lower than those of alcohols of comparable molecular weight and slightly higher than those of hydrocarbons of comparable molecular weight (Table 1).
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