Double in Situ Preparation of Raspberry-like Polymer Particles

Well-defined raspberry-like poly(styrene- co-4-vinylpyridine)-SiO₂ nanocomposite particles with a diameter of around 200 nm were easily prepared by a double in situ process in nanoemulsion with the water-soluble dye Eosin Y as the stabilizer. During radical polymerization of the nanodroplets comprising styrene, 4-vinylpyridine (4-VP), and tetraethoxysilane (TEOS), the silane phase is expelled from the polymer phase to the oil/water (o/w) interface. In the later polymerization stage, SiO₂ nanoparticles with a size of around 25 nm were produced via the in situ sol-gel reaction of TEOS at the o/w interface promoted by the negatively charged dye. The pyridine moieties in the copolymer fix the SiO₂ nanoparticles on the surface of the polymer particles by electrostatic interactions without any sign of free unbound silica particles as proven by transmission electron microscopy.