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Updated: Jan 26, 2026

Hydrogen Production and Utilization in a Membrane Reactor
Published on: March 10, 2023
Oscillations of pH in the urea-urease system in a membrane reactor
František Muzika1, Matěj RůŽička, Lenka Schreiberová
1Department of Chemical Engineering, University of Chemistry and Technology, Prague, Technická 5, 166 28 Praha 6, Czech Republic. igor.schreiber@vscht.cz.
Abstract:
Herein, we present direct experimental evidence of pH oscillatory dynamics in the urea-urease enzymatic reaction conducted in a continuous reactor-membrane-reservoir system. Our results are consistent with earlier model predictions requiring differential transport of H+ and substrate. We report oscillations with periods in hundreds of seconds and the amplitude of ∼0.1 pH units.
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