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Updated: Jan 26, 2026

Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
Published on: June 23, 2023
Tandem catalysis by ultrathin metal-organic nanosheets formed through post-synthetic functionalisation of a layered
Joshua Nicks1, Jiawen Zhang, Jonathan A Foster
1Department of Chemistry, University of Sheffield, Sheffield, UK. jona.foster@sheffield.ac.uk.
Abstract:
Covalent post-synthetic functionalisation of layered metal-organic frameworks is demonstrated as a new approach to forming ultrathin nanosheets for use in catalysis. An aminoterephthalate framework was partially functionalised with sulfonate chains and exfoliated to form predominantly monolayer nanosheets able to catalyse a two-step acid-base reaction in one pot.
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