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A [C1 + C2] route to propargylidyne complexes.

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New tungsten propargylidynes and complex poly-tungsten-gold structures were synthesized using terminal alkynes and organometallic precursors. These reactions expand the scope of organotungsten chemistry and metal-alkyne couplings.

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Area of Science:

  • Organometallic Chemistry
  • Tungsten Chemistry
  • Alkyne Chemistry

Background:

  • Tungsten carbynes are versatile building blocks in organometallic synthesis.
  • Palladium and copper catalysis are widely used for alkyne functionalization.

Purpose of the Study:

  • To synthesize novel tungsten-containing propargylidynes and poly-metallic complexes.
  • To explore the reactivity of a tungsten-alkynyl bromide precursor with various alkynes and organometallic reagents.

Main Methods:

  • Reaction of [W(CBr)(CO)2(Tp*)] with terminal alkynes under palladium/copper catalysis.
  • Synthesis of ditungsten and tetrametallic complexes via alkyne coupling and reaction with gold complexes.

Main Results:

  • Formation of new propargylidynes [W(C-C≡CR)(CO)2(Tp*)] with diverse R groups.
  • Synthesis of a ditungstaoctatetrayne and a tetrametallic tungsten-gold complex.

Conclusions:

  • The tungsten alkynyl bromide precursor is a versatile synthon for constructing complex organotungsten and polymetallic architectures.
  • The study demonstrates efficient methods for incorporating diverse organic fragments and multiple metal centers into tungsten frameworks.