Bismuth-Based Photocatalysts for Solar Photocatalytic Carbon Dioxide Conversion

Photocatalytic CO₂ conversion into solar fuels is an effective means for simultaneously solving both the greenhouse effect and energy crisis. In the past ten years, bismuth-based photocatalysts for environmental remediation have experienced a golden period of development. However, solar photocatalytic CO₂ conversion has only been developed over the past five years and, until now, no reviews have been published on bismuth-based photocatalysts for the photocatalytic conversion of CO₂ . For the first time, solar photocatalytic CO₂ conversion systems are reviewed herein. Synthetic methods and photocatalytic CO₂ performances of bismuth-based photocatalysts, including Sillén-structured BiOX (X=Cl, Br, I); Aurivillius-structured Bi₂ MO₆ (M=Mo, W); and Scheelite-structured BiVO₄ , Bi₂ S₃ , BiYO₃ , and BiOIO₃ , are summarized. In addition, activity-enhancing strategies for this photocatalyst family, including oxygen vacancies, bismuth-rich strategy, facet control, conventional type II heterojunction, Z-scheme heterojunction, and cocatalyst deposition, are reviewed. Finally, the main mechanistic research methods, such as in situ FTIR spectroscopy and theoretical calculations, are presented. Challenges and research trends reported in studies of bismuth-based photocatalysts for photocatalytic CO₂ conversion are discussed and summarized.