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Related Concept Videos

Electron Configuration of Multielectron Atoms03:26

Electron Configuration of Multielectron Atoms

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The alkali metal sodium (atomic number 11) has one more electron than the neon atom. This electron must go into the lowest-energy subshell available, the 3s orbital, giving a 1s22s22p63s1 configuration. The electrons occupying the outermost shell orbital(s) (highest value of n) are called valence electrons, and those occupying the inner shell orbitals are called core electrons. Since the core electron shells correspond to noble gas electron configurations, we can abbreviate electron...
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An atom comprises protons and neutrons, which are contained inside the dense, central core called the nucleus, with electrons present around the nucleus. Taking into account the wave–particle duality of electrons and the uncertainty in position around the nucleus, quantum mechanics provides a more accurate model for the atomic structure. It describes atomic orbitals as the regions around the nucleus where electrons of discrete energy exist, characterized by four quantum...
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Atomic Structure

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Atomic Orbitals02:44

Atomic Orbitals

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An atomic orbital represents the three-dimensional regions in an atom where an electron has the highest probability to reside. The radial distribution function indicates the total probability of finding an electron within the thin shell at a distance r from the nucleus. The atomic orbitals have distinct shapes which are determined by l, the angular momentum quantum number. The orbitals are often drawn with a boundary surface, enclosing densest regions of the cloud.
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The mathematical expression known as the wave function, ψ, contains information about each orbital and the wavelike properties of electrons in an isolated atom. When atoms are bound together in a molecule, the wave functions combine to produce new mathematical descriptions that have different shapes. This process of combining the wave functions for atomic orbitals is called hybridization and is mathematically accomplished by the linear combination of atomic orbitals. The new orbitals that...
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The Energies of Atomic Orbitals

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In an atom, the negatively charged electrons are attracted to the positively charged nucleus. In a multielectron atom, electron-electron repulsions are also observed. The attractive and repulsive forces are dependent on the distance between the particles, as well as the sign and magnitude of the charges on the individual particles. When the charges on the particles are opposite, they attract each other. If both particles have the same charge, they repel each other.
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Updated: Jan 24, 2026

All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics
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All-electronic Nanosecond-resolved Scanning Tunneling Microscopy: Facilitating the Investigation of Single Dopant Charge Dynamics

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Engineering single-atom dynamics with electron irradiation.

Cong Su1,2, Mukesh Tripathi3, Qing-Bo Yan4

  • 1Department of Nuclear Science and Engineering and Department of Materials Science and Engineering, Massachusetts Institute of Technology, Cambridge, MA 02139, USA.

Science Advances
|May 23, 2019
PubMed
Summary
This summary is machine-generated.

Electron irradiation enables atomic engineering by controlling single atom dynamics in graphene. This study predicts and experimentally validates how electron collisions influence phosphorus dopant configurations for targeted atomic manipulation.

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Area of Science:

  • Materials Science
  • Condensed Matter Physics
  • Nanotechnology

Background:

  • Atomic engineering aims to control individual atom behavior for creating advanced materials.
  • Electron irradiation is a powerful tool for manipulating atoms at the nanoscale.
  • Understanding the dynamics of dopants in graphene is crucial for its applications.

Purpose of the Study:

  • To investigate the single-step dynamics of phosphorus dopants in graphene under electron irradiation.
  • To develop a theoretical framework predicting the outcomes of atomic collisions.
  • To enable precise control over atomic configurations for future material design.

Main Methods:

  • Atomically resolved experimental observations of electron-irradiated graphene.
  • Computational simulations of primary knock-on atom (PKO) collisions.
  • Theoretical modeling of configurational outcome probabilities based on PKO momentum.

Main Results:

  • The study successfully surveyed the dynamics of single phosphorus dopants in graphene.
  • A theory was developed to predict the probabilities of different atomic configurations post-collision.
  • Predicted branching ratios for configurational transformations closely matched experimental results.

Conclusions:

  • Electron irradiation can be used to selectively control the dynamics of single atoms in graphene.
  • The developed theory provides a pathway for biasing atomic dynamics toward desired outcomes.
  • This research paves the way for designing and scaling atomic engineering techniques.