Fouling and wetting in the membrane distillation driven wastewater reclamation process - A review

Fouling and wetting of membranes are significant concerns that can impede the widespread application of the membrane distillation (MD) process during high-salinity wastewater reclamation. Fouling, caused by the accumulation of undesirable materials on the membrane surface and pores, causes a decrease in permeate flux. Membrane wetting, the direct permeation of the feed solution through the membrane pores, results in reduced contaminant rejection and overall process failure. Lately, the application of MD for water recovery from various types of wastewaters has gained increased attention among researchers. In this review, we discuss fouling and wetting phenomena observed during the MD process, along with the effects of various mitigation strategies. In addition, we examine the interactions between contaminants and different types of MD membranes and the influence of different operating conditions on the occurrence of fouling and wetting. We also report on previously investigated feed pre-treatment options before MD, application of integrated MD processes, the performance of fabricated/modified MD membranes, and strategies for MD membrane maintenance during water reclamation. Energy consumption and economic aspects of MD for wastewater recovery is also discussed. Throughout the review, we engage in dialogues highlighting research needs for furthering the development of MD: the incorporation of MD in the overall wastewater treatment and recovery scheme (including selection of appropriate membrane material, suitable pre-treatment or integrated processes, and membrane maintenance strategies) and the application of MD in long-term pilot-scale studies using real wastewater.