V2Se: a novel antifluorite-type cubic phase with a metal-metal bonding
1Max Planck Institute for Chemical Physics of Solids, Nöthnitzer Str. 40, D-01187, Dresden, Germany. rlgns111@gmail.com and Max Planck Institute for Solid State Research, Heisenbergstraße 1, D-70569, Stuttgart, Germany.
Dalton Transactions (Cambridge, England : 2003)
|May 30, 2019
Abstract:
A new antifluorite-type (Li2O-type) cubic compound, V2Se, has been synthesized for the first time by changing the amount of selenium in chemical vapor transport. The vanadium-based cubic phase studied here reveals a metal-metal bonding feature in the electronic band structure. This compound is the first example of an antifluorite-type cubic structure in a V-Se system.
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