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Sample Consensus Model and Unsupervised Variable Consensus Model for Improving the Accuracy of a Calibration Model.

Zhou Xu1, Xiaojing Chen2, Liuwei Meng3

  • 11 National and Local Joint Engineering Research Center of Reliability Analysis and Testing for Mechanical and Electrical Products, Zhejiang Sci-Tech University, Hangzhou, China.

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|June 1, 2019
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Summary
This summary is machine-generated.

Two consensus modeling methods improve spectral data calibration accuracy by leveraging sample and variable information, overcoming challenges of small sample sizes and high dimensionality in quantitative analysis.

Keywords:
Consensus strategyKohonen self-organizing maphigh-dimension variablepartial least squares regressionsmall sample size

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Area of Science:

  • Quantitative analysis
  • Chemometrics
  • Spectroscopy

Background:

  • Small sample size and high dimensionality in spectral data analysis often reduce calibration model accuracy.
  • Partial Least Squares Regression (PLSR) is a common but sometimes limited method for spectral data.
  • Developing robust calibration models is crucial for accurate quantitative analysis of spectral data.

Purpose of the Study:

  • To address the poor accuracy of calibration models caused by small sample size and high dimensionality.
  • To propose and evaluate two novel consensus modeling strategies: sample consensus and unsupervised variable consensus models.
  • To enhance the predictive performance of quantitative spectral analysis.

Main Methods:

  • Developed sample consensus and unsupervised variable consensus models.
  • Utilized Partial Least Squares Regression (PLSR) as the base modeling technique.
  • Employed Monte Carlo sampling and self-organizing map (SOM) for unsupervised variable clustering.
  • Applied consensus modeling strategy by weighting multiple PLSR sub-models.

Main Results:

  • Both sample consensus and unsupervised variable consensus models significantly improved calibration model accuracy.
  • The proposed methods demonstrated superior performance compared to a single PLSR model.
  • Effectiveness was validated using three public near-infrared (NIR) or infrared (IR) spectroscopy datasets (corn, wine, soil).

Conclusions:

  • Sample and unsupervised variable consensus models offer a new approach for accurate quantitative spectral analysis.
  • These methods effectively utilize both sample and variable information for improved model performance.
  • The findings provide a pathway to achieve more accurate results in spectral data analysis.