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Related Concept Videos

Formation of Complex Ions03:45

Formation of Complex Ions

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A type of Lewis acid-base chemistry involves the formation of a complex ion (or a coordination complex) comprising a central atom, typically a transition metal cation, surrounded by ions or molecules called ligands. These ligands can be neutral molecules like H2O or NH3, or ions such as CN− or OH−. Often, the ligands act as Lewis bases, donating a pair of electrons to the central atom. These types of Lewis acid-base reactions are examples of a broad subdiscipline called coordination...
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In a precipitation reaction, aqueous solutions of soluble salts react to give an insoluble ionic compound – the precipitate. The reaction occurs when oppositely charged ions in solution overcome their attraction for water and bind to each other, forming a precipitate that separates out from the solution. Since such reactions involve the exchange of ions between ionic compounds in aqueous solution, they are also referred to as double displacement, double replacement, exchange reactions, or...
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Concentration Cells

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A concentration cell is a type of a  voltaic cell constructed by connecting two almost identical half-cells, both based on the same half-reaction and using the same electrode, differing only in the concentration of one redox species. A concentration cell's potential, therefore, is determined only by the concentration difference of the particular redox species.
Consider the following voltaic cell:
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Spontaneous Chemical Reactions
Spontaneous redox reactions occur abundantly in nature. The chemical reaction occurring in a disposable AA battery powering our remote controls is one such example of a spontaneous redox reaction. Another example is the immersion of coiled copper wire into an aqueous silver nitrate solution. The reaction shows a gradual, visually impressive color change from colorless to bright blue and the formation of a grey precipitate on the copper wire. In this experiment,...
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Solubility of Ionic Compounds02:55

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Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
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Molar Mass01:54

Molar Mass

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The identity of a substance is defined not only by the types of atoms or ions it contains but by the quantity of each type of atom or ion. For example, water, H2O, and hydrogen peroxide, H2O2, are alike in that their respective molecules are composed of hydrogen and oxygen atoms. However, because a hydrogen peroxide molecule contains two oxygen atoms, as opposed to the water molecule, which has only one, the two substances exhibit very different properties.
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Fabrication of Thin Film Silver/Silver Chloride Electrodes with Finely Controlled Single Layer Silver Chloride
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Fulminating Gold and Silver.

Curt Wentrup1

  • 1School of Chemistry and Molecular Biosciences, The University of Queensland, Brisbane, Queensland, 4072, Australia.

Angewandte Chemie (International Ed. in English)
|June 5, 2019
PubMed
Summary
This summary is machine-generated.

This essay explores the explosive properties of fulminating gold and silver compounds. Historically, alchemists sought to use these compounds to create a tincture for transmuting metals and curing illnesses.

Keywords:
Aurum potabilealchemyargent fulminantaurum fulminansiatrochemistry

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Area of Science:

  • Historical Chemistry
  • Alchemy
  • Explosive Compounds

Background:

  • Fulminating gold and silver are highly explosive compounds.
  • Their preparation involves reacting gold or silver compounds with ammonia.
  • These substances fascinated alchemists from the 16th to 18th centuries.

Purpose of the Study:

  • To examine the historical significance and properties of fulminating gold and silver.
  • To understand alchemists' attempts to utilize these compounds for transmutation and medicinal purposes.

Main Methods:

  • Review of historical alchemical texts and preparations.
  • Analysis of the chemical reactions involved in creating fulminating gold and silver.
  • Discussion of the likely composition of early preparations (e.g., gold chlorides).

Main Results:

  • Fulminating gold and silver are readily synthesized using ammonia.
  • Alchemists extensively documented preparations and attempted to create volatile gold compounds.
  • These efforts were driven by the desire for a universal panacea and metal transmutation.

Conclusions:

  • Fulminating compounds represent a significant, albeit dangerous, area of historical chemical investigation.
  • Alchemists' pursuit of these substances highlights early attempts at chemical manipulation for profound goals.
  • The compounds, likely gold chlorides, were central to alchemical theories of healing and transformation.