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Sydnone Photochemistry: Formation of Nitrenes

Didier Bégué1, Maryam Miri2, Avat Arman Taherpour2

  • 1CNRS/Université de Pau et des Pays de l'Adour/E2S UPPA, Institut des Sciences Analytiques et de Physicochimie pour l'Environnement et les Matériaux, UMR5254, Pau 64000, France.

The Journal of Organic Chemistry
|August 15, 2025
PubMed
Summary

Photolysis of sydnones generates triplet arylnitrenes. Imidoylnitrenes are key intermediates, dissociating to form nitrenes and nitriles or rearranging to carbodiimides.

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