Achieving high-efficiency purely organic room-temperature phosphorescence materials by boronic ester substitution of
Mengke Li1, Xinyi Cai1, Zhenyang Qiao1
1State Key Laboratory of Luminescent Materials and Devices, Institute of Polymer Optoelectronic Materials and Devices, South China University of Technology, Guangzhou 510640, P. R. China. mssjsu@scut.edu.cn.
Abstract:
The effect of boronic ester substitution on the room-temperature phosphorescence properties of phenoxathiine-based derivatives was thoroughly investigated. A significantly improved phosphorescence quantum efficiency of up to 20% in the crystalline state was achieved by delicate molecular manipulation for both enhanced spin-orbital coupling and compact intermolecular packing.
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