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Published on: May 22, 2015
Atomic-layer-deposition-formed sacrificial template for the construction of an MIL-53 shell to increase selectivity
Tiantian Xu1, Kai Sun, Daowei Gao
1School of Chemistry and Chemical Engineering, University of Jinan, Shandong Province 255022, China. chm_chengz@ujn.edu.cn.
Abstract:
We developed a method for using atomic layer deposition (ALD)-formed layers of Al2O3 as a sacrificial template to generate MIL-53(Al). The MOF shell in the CeO2/Pd@MIL-53(Al) configuration not only stabilized the Pd nanoparticles, but also regulated the selectivity of the hydrogenation of unsaturated aldehydes. This work represents the first demonstration of ALD-formed layers of metal oxides serving as sacrificial templates in the design of MOF-shell-based sandwich-type structures.
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