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Retropinacol/Cross-pinacol Coupling Reactions - A Catalytic Access to 1,2-Unsymmetrical Diols
Published on: April 4, 2014
A weakly basic Co/CeOx catalytic system for one-pot conversion of cellulose to diols: Kungfu on eggs
Chuang Li1, Guangyue Xu1, Kui Li1
1Hefei National Laboratory for Physical Sciences at the Microscale, CAS Key Laboratory of Urban Pollutant Conversion, Anhui Province Key Laboratory of Biomass Clean Energy, iChEM, University of Science and Technology of China, Hefei, Anhui 230026, China. fuyao@ustc.edu.cn zhzhying@ustc.edu.cn.
Abstract:
A controlled, weakly basic Co/CeOx catalyst was designed for one-pot conversion of cellulose to ethylene glycol (EG) and 1,2-propylene glycol (1,2-PG) to achieve near-equivalent yield. The efficiency is mainly attributed to Con+-Ox-Ce3+ base-acid pairs that hindered humin formation by ensuring a precise balance across the various steps of the reaction.
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