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Updated: Jan 23, 2026
Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
Published on: September 8, 2013
Dataset on synthesis and crystallographic structure of phenyl(TMP)iodonium(III) acetate
Hideyasu China1, Daichi Koseki1, Kazuki Samura1
1College of Pharmaceutical Science, Ritsumeikan University, 1-1-1 Nojihigashi, Kusatu, Shiga, 525-8577, Japan.
Abstract:
The data in this article are related to research article ''Efficient N-arylation of azole compounds utilizing selective aryl-transfer TMP-iodonium (III) reagents (Koseki et al., 2019). For the title compound, phenyl(2,4,6-trimethoxyphenyl)iodonium(III) acetate (Ph(TMP)IOAc), the single-crystal X-ray diffraction measurement together with NMR analysis, like also the method of synthesis and crystallization are presented. The X-ray structure analysis has revealed that the two types of geometries regarding the acetate anion attached to phenyl (TMP)iodonium (III) cation are found in the crystal states.
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