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Updated: Jan 23, 2026

Photochemical Oxidative Growth of Iridium Oxide Nanoparticles on CdSe@CdS Nanorods
Published on: February 11, 2016
Evidence for tetranuclear bis-μ-oxo cubane species in molecular iridium-based water oxidation catalysts from XAS
Stuart A Bartlett1, Emma V Sackville, Emma K Gibson
1Diamond Light Source, Harwell Science and Innovation Campus, Didcot OX11 0DE, UK. stuart.bartlett@diamond.ac.uk.
Abstract:
The structure of a highly active pyridine-alkoxide iridium water oxidation catalyst (WOC) is examined by X-ray absorption spectroscopy (XAS). A detailed comparison with IrO2 points to a rigid molecular unit of low nuclearity, with the best analysis suggesting a novel tetrameric iridium-oxo cubane as the resting state.
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