Simultaneous and interference-free measurements of temperature and C₂H₄ concentration using a single tunable diode...

In the tunable diode laser absorption spectroscopy-based diagnostics, the absorption of the measured target species may be influenced by the interference absorption from other vapor-phase species and the extinction from particles and liquid droplets, especially at high temperatures and pressures. Here, we report the first application (to our knowledge) of a differential absorption diagnostic for interference-free, simultaneous measurement of temperature and ethylene concentration using a single distributed-feedback diode laser near 1.62 μm. According to the detailed study of the C₂H₄ spectra in this region, two wavelength pairs are chosen to measure the temperature based on six selection criteria. C₂H₄ concentration is measured by one of the selected wavelength pairs with higher differential absorption. To validate the developed system, experiments are performed in a well-controlled heated static cell at a range of temperatures (300-900 K) and pressures (1-6 atm). The measurement accuracies for temperature and ethylene concentration are 1.83% and 1.65%, respectively, over the considered ranges. The precision, stability, and detection limit are also analyzed to validate the system's performance. This system can potentially be applied in a variety of combustion applications.