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Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
Negatively charged metal-organic hosts with cobalt dithiolene species: improving PET processes for light-driven
Junkai Cai1, Liang Zhao1, Jianwei Wei1
1State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, 116024, P. R. China. zhaol@dlut.edu.cn cyduan@dlut.edu.cn.
Abstract:
By incorporating 1,2-benzenedithiol as a chelator to construct cobalt dithiolene species, two negatively charged redox-active metal-organic hosts were obtained. By taking advantage of electrostatic interactions, cationic Ru-based photosensitizers were constrained to improve photoinduced electron transfer processes for efficient photocatalytic proton reduction.
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