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Tuning Pd-nanoparticle@MIL-101(Cr) Catalysts for Tandem Reductive Amination.

Amanda E Anderson1, Christopher J Baddeley1, Paul A Wright1

  • 1EaStCHEM School of Chemistry, University of St Andrews, Purdie Building, North Haugh, St. Andrews, Fife KY16 9ST UK.

Catalysis Letters
|July 2, 2019
PubMed
Summary

Metal-organic frameworks (MOFs) enable efficient one-pot tandem reductive amination. Tuning the ratio of palladium nanoparticles to Lewis acidic chromium sites in MIL-101(Cr) controls selectivity for secondary amine products.

Keywords:
Kinetic modellingPd@MIL-101Tandem reductive amination

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