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Updated: Jan 22, 2026

From Molecules to Materials: Engineering New Ionic Liquid Crystals Through Halogen Bonding
Published on: March 24, 2018
Halogen-bond mediated efficient storage of extremely volatile perfluoroiodides in ionic liquids
Delphine Gaspard1, Kenneth R Seddon, Peter K J Robertson
1The QUILL Research Centre, School of Chemistry and Chemical Engineering, Queen's University Belfast, UK. n.gunaratne@qub.ac.uk.
Abstract:
Highly volatile and valuable reagents, perfluoroiodides were shown to complex with ionic liquids with the aid of a halogen-bond between a diverse set of anions and the electrophilic iodine atoms in perfluorinated iodides. The affinity of anions in various ionic liquids towards perfluoroiodides was examined by 19F NMR. Making use of the non-volatility of ionic liquids, we demonstrate here that perfluoroiodides can be stored and released controllably, on demand, from an ionic liquid matrix.
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