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Molecular Auger Interferometry.

M A Khokhlova1, B Cooper2, K Ueda3

  • 1Blackett Laboratory, Imperial College London, London SW7 2AZ, United Kingdom.

Physical Review Letters
|July 13, 2019
PubMed
Summary
This summary is machine-generated.

We developed molecular Auger interferometry to measure Auger decay lifetimes. This technique uses a two-color laser field to control Auger dynamics, enabling lifetime extraction without complex spectroscopy.

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Area of Science:

  • Molecular Physics
  • Quantum Chemistry
  • Spectroscopy

Background:

  • Auger decay is a fundamental process in molecular physics.
  • Measuring Auger decay lifetimes in molecules is crucial for understanding electron dynamics.
  • Current methods often require high-resolution or attosecond spectroscopy.

Purpose of the Study:

  • To introduce a novel theory for interferometric measurement of molecular Auger decay lifetimes.
  • To demonstrate a method for extracting Auger lifetimes without advanced spectroscopic techniques.
  • To validate the theory using inner-valence decay in methyl fluoride (CH3F).

Main Methods:

  • Developing a theory of molecular Auger interferometry.
  • Utilizing a two-color (ω/2ω) laser field for coherent phase control of Auger dynamics.
  • Analyzing the modulation of total ionization yield by the relative phase in oriented molecules.

Main Results:

  • The relative phase in a two-color laser field modulates the total ionization yield in oriented molecules.
  • A simple analytical formula was derived to extract Auger lifetimes from interferograms.
  • The principle was successfully demonstrated using inner-valence decay in CH3F.

Conclusions:

  • Molecular Auger interferometry provides a new pathway for determining Auger decay lifetimes.
  • This method circumvents the need for high-resolution or attosecond spectroscopy.
  • The technique offers a simpler approach to studying ultrafast electron dynamics in molecules.