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Updated: Jan 22, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
New insights into solvent-induced structural changes of 13C labelled metal-organic frameworks by solid state NMR
Marcus Rauche1, Sebastian Ehrling, Simon Krause
1Chair of Bioanalytical Chemistry, TU Dresden, D-01062 Dresden, Germany. eike.brunner@tu-dresden.de.
Abstract:
Selective 13C-labelling of carboxylate carbons in the linker molecules of flexible metal-organic frameworks (MOFs) makes solid-state NMR spectroscopy very powerful to investigate solvent-induced local structural changes as demonstrated by 13C and 1H NMR spectroscopy on the pillared layer MOF DUT-8(Ni). Selective identification of polar solvent-node interactions becomes feasible.
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