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Superior Photo-thermionic electron Emission from Illuminated Phosphorene Surface
S Madas1, S K Mishra1,2, S Kahaly3
1ELI-ALPS, ELI-HU Non-Profit Ltd., Dugonics ter 13, Szeged, 6720, Hungary.
Scientific Reports
|July 18, 2019
Summary
Black phosphorene shows potential as an efficient photo-thermionic emitter. Photon irradiation significantly enhances emission flux, with structural anisotropy playing a key role in boosting performance for energy converters.
Area of Science:
- Materials Science
- Condensed Matter Physics
- Quantum Mechanics
Background:
- Black phosphorene, a 2D allotrope of phosphorus, is explored for novel electronic properties.
- Thermionic and photo-thermionic emission are crucial processes in energy conversion technologies.
Purpose of the Study:
- To investigate the potential of black phosphorene as an efficient photo-thermionic emitter.
- To develop a theoretical framework for understanding and enhancing electron emission from phosphorene.
Main Methods:
- Utilizing ab initio quantum simulations (density functional theory) to study phosphorene's band structure.
- Employing semiclassical descriptions for modeling the thermionic and photo-thermionic emission processes.
- Estimating material-specific parameters like Fermi level and work function.
Main Results:
- Established a formalism for calculating thermionic electron emission current from phosphorene.
- Demonstrated substantial enhancement of emission current under photon irradiation.
- Observed photoemission flux dominating thermionic emission, with phosphorene's anisotropy significantly boosting flux.
Conclusions:
- Black phosphorene is a promising material for efficient photo-thermionic emission.
- Photon irradiation and structural anisotropy are key factors for enhancing emission.
- Results suggest potential applications in phosphorene-based thermionic and photo-thermionic energy converters.
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