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A Step Beyond BRET: Fluorescence by Unbound Excitation from Luminescence FUEL
Published on: May 23, 2014
Microlens array enhanced upconversion luminescence at low excitation irradiance
Qingyun Liu1, Haichun Liu2, Deyang Li3
1Department of Theoretical Chemistry and Biology, KTH Royal Institute of Technology, Stockholm, Sweden. hagren@kth.se haichun@kth.se and School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin, P.R. China. chenguanying@hit.edu.cn.
Microlens arrays (MLAs) boost lanthanide-doped upconversion nanoparticle (UCNP) luminescence intensity by over 100x. This spatial light modulation technique enhances UCNP applications in bioimaging and photovoltaics.
Area of Science:
- Materials Science
- Nanotechnology
- Photonics
Background:
- Lanthanide-doped upconversion nanoparticles (UCNPs) exhibit low luminescence intensity at low excitation, limiting their applications.
- Upconversion luminescence (UCL) intensity is nonlinearly dependent on excitation irradiance.
Purpose of the Study:
- To enhance UCL intensity from UCNPs using microlens arrays (MLAs).
- To investigate the impact of MLAs on multicolored UCL from core/shell UCNPs.
- To demonstrate the potential of MLA-enhanced UCNPs in devices like solar cells.
Main Methods:
- Utilized polymeric microlens arrays (MLAs) as spatial light modulators.
- Investigated multicolored UCL from NaYF4:Yb3+,Er3+@NaYF4:Yb3+,Nd3+ and NaYF4:Yb3+,Tm3+@NaYF4:Yb3+,Nd3+ core/shell UCNPs.
- Employed ray tracing simulations to understand light field manipulation by MLAs.
Main Results:
- Achieved over one order of magnitude increase in UCL intensity using MLAs.
- Observed distinct enhancement factors for green, red (Er3+), and blue (Tm3+) UCL bands.
- Demonstrated a 225-fold amplification of Tm3+ UCL at low excitation irradiance.
Conclusions:
- MLAs effectively enhance UCL intensity by spatially confining excitation light.
- The MLA method significantly improves the performance of UCNP-based devices.
- This technique offers a promising pathway for advancing UCNP applications in various fields.
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