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Related Concept Videos

Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Theoretical Calculation and Experimental Verification for Dislocation Reduction in Germanium Epitaxial Layers with Semicylindrical Voids on Silicon
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√7  ×  √3 surface with a double layer of In on Si(1 1 1) exhibiting both hexagonal and rectangular features.

Jeongseok Woo1, Hyungjoon Shim1, Geunseop Lee1

  • 1Department of Physics, Inha University, 100 Inha-ro, Michuhol-gu, Incheon 22212, Republic of Korea.

Journal of Physics. Condensed Matter : an Institute of Physics Journal
|July 20, 2019
PubMed
Summary

The study reveals that the hexagonal and rectangular In-induced phases on Silicon(111) are the same double-layer structure. This finding challenges previous assumptions about distinct surface phases and In coverage.

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Area of Science:

  • Surface Science
  • Materials Science
  • Nanotechnology

Background:

  • The Si(111) surface is a well-studied substrate for thin film growth.
  • Indium (In) deposition on Si(111) can form various surface reconstructions.
  • Previously, √7×√7 and √7×√7 phases were thought to represent different In coverages.

Purpose of the Study:

  • To investigate the structural relationship between the In-induced √7×√7-hex and √7×√7-rect phases on Si(111).
  • To determine the actual In coverage and structure responsible for these observed surface phases.
  • To clarify the prevailing understanding of In/Si(111) surface reconstructions.

Main Methods:

  • Scanning Tunneling Microscopy (STM) was employed to image the surface structures.
  • Bias-dependent STM imaging was used to analyze the electronic properties of the domains.
  • In-situ observations of island formation on different phases provided thickness information.

Main Results:

  • Both √7×√7-hex and √7×√7-rect features were observed within the same domain using bias-dependent STM.
  • The formation of a √7×√7-hex island on a √7×√7-'striped' (single-layer In) phase suggests a double-layer In structure for the √7×√7 phases.
  • A long-range Moiré-like superstructure was observed, attributed to lattice mismatch between In and Si(111).

Conclusions:

  • The In-induced √7×√7-hex and √7×√7-rect phases on Si(111) originate from the same double-layer In structure.
  • This finding contradicts the existing notion of two distinct √7×√7 surfaces with different In coverages.
  • The observed Moiré superstructure is a consequence of the epitaxial relationship between the In double layer and the Si(111) substrate.