A boron nitride electrode modified with a nanocomposite prepared from an ionic liquid and tungsten disulfide for...

Boron nitride (BN) was used as a support and covered with an ionic liquid (IL) and tungsten disulfide (WS₂) nanoparticles to obtain an electrode for the determination of 4-aminophenol (4-AP). BN was prepared using a "solvent cutting" method, and the BN-IL-WS₂ nanocomposite was obtained by an ultrasonic method. BN and its hybrids were characterized by scanning electron microscopy, transmission electron microscopy and X-ray diffraction. When the BN-IL-WS₂ composites were coated on the surface of the electrode, the response to 4-AP was strongly amplified due to the strong synergetic effect between the three materials. The voltammetric response of the modified sensor (with a maximum at 0.29 V vs. Ag/AgCl) in solutions with a pH of 6 is linear in the 0.01-50 μΜ 4-AP concentration range, and the limit of detection is 3 nM. A modified glassy carbon electrode was applied for the determination of 4-AP in seawater and dispersions containing paracetamol tablets. The results were consistent with those obtained by HPLC. Graphical abstract Schematic representation of the voltammetric determination process of 4-aminophenol (4-AP). The electrochemical sensor based on the glassy carbon electrode modified with boron nitride (BN), ionic liquid (IL) and tungsten disulfide (WS₂) nanomaterials. They, exhibit an excellent performance compared with other electrodes.