Fixed-bed adsorption of copper from aqueous media using chitosan-coated bentonite, chitosan-coated sand, and...

Fixed-bed studies were performed to evaluate the removal efficiency of copper (Cu(II)) from aqueous solution using chitosan-coated bentonite (CCB), chitosan-coated sand (CCS), and chitosan-coated kaolinite (CCK). The thermal and morphological properties of CCB, CCK, and CCS were characterized using thermogravimetric analysis, Fourier transform infrared spectroscopy, and the Brunauer-Emmett-Teller method. Dynamic experiments were carried out to investigate the effect of solution pH (3.0 to 5.0) and initial Cu(II) concentration (200 to 1000 mg/L) on the time to reach breakthrough (t_b), total volume of treated effluent (V_eff), and adsorption capacity at breakthrough (q_b). Results show that increasing the initial Cu(II) concentration inhibits the column performance where lower V_eff, t_b, and q_b were obtained. Decreasing the pH from 5.0 to 3.0 led to improved removal efficiency with higher values of V_eff, t_b, and q_b. Under pH 3.0 and 200 mg/L, the maximum removal efficiency of 68.60%, 56.10%, and 58.90% for Cu(II) was attained using CCB, CCS, and CCK, respectively. The Thomas model was determined to adequately predict the breakthrough curves based on high values of coefficient of determination (R² ≥ 0.8503). Regeneration studies were carried out using 0.1 M HCl and 0.1 M NaOH solution in the saturated column of CCB, CCK, and CCS.