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Updated: Jan 20, 2026

Molten-Salt Synthesis of Complex Metal Oxide Nanoparticles
Published on: October 27, 2018
Synthesis and Utility of Neptunium(III) Hydrocarbyl Complex
Alexander J Myers1, Michael L Tarlton1, Steven P Kelley1
1Department of Chemistry, University of Missouri, Columbia, 601 S. College Avenue, Columbia, MO, 65211, USA.
Abstract:
To extend organoactinide chemistry beyond uranium, reported here is the first structurally characterized transuranic hydrocarbyl complex, Np[η4 -Me2 NC(H)C6 H5 ]3 (1), from reaction of NpCl4 (DME)2 with four equivalents of K[Me2 NC(H)C6 H5 ]. Unlike the UIII species, the neptunium analogue can be used to access other NpIII complexes. The reaction of 1 with three equivalents of HE2 C(2,6-Mes2 -C6 H3 ) (E=O, S) yields [(2,6-Mes2 -C6 H3 )CE2 ]3 Np(THF)2 , maintaining the trivalent oxidation state.
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