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Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
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Fabricating Metamaterials Using the Fiber Drawing Method
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Metamaterial for Hydrogen Sensing.

Takaaki Beni, Naoki Yamasaku, Takuma Kurotsu

  • 1Centre for Micro-Photonics, Faculty of Science, Engineering and Technology , Swinburne University of Technology , Hawthorn , VIC 3122 , Australia.

ACS Sensors
|August 16, 2019
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Summary

This study presents a novel hydrogen sensor using plasmonic metasurfaces. The sensor achieves a 10-second reaction time and high sensitivity for detecting hydrogen gas.

Keywords:
hydrogen reactive materialshydrogen sensormetasurfacesoptical detectionplasmon absorbersplasmonics

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Area of Science:

  • Nanotechnology
  • Materials Science
  • Chemical Sensing

Background:

  • Plasmonic metasurfaces offer unique optical properties for sensing applications.
  • Developing fast and sensitive hydrogen sensors is crucial for various industrial and safety applications.

Purpose of the Study:

  • To demonstrate a hydrogen sensor based on plasmonic metasurfaces with industry-required performance.
  • To investigate the sensor's mechanism and potential for other molecular detection.

Main Methods:

  • Fabrication of a metasurface sensor with Y or WO3 phase change layer, Pd nanodisk, and Au mirror.
  • Detection of hydrogen via spectral shift in reflectance due to refractive index change.
  • Numerical modeling to analyze refractive index effects on spectral shifts.

Main Results:

  • The sensor achieved the industry-required 10 s reaction time and high sensitivity.
  • Direct reflectance readout of permittivity change was enabled by field enhancement.
  • Spectral shifts correlated with hydrogen uptake and refractive index changes.

Conclusions:

  • The plasmonic metasurface sensor effectively detects hydrogen with excellent performance.
  • The design is tunable for operation wavelength and applicable to other molecular sensing, including surface-enhanced IR absorption.