Adsorption of tetracycline in aqueous solution by biochar derived from waste Auricularia auricula dregs

This study investigated the adsorption of tetracycline (TC) on biochar (BC) derived from waste Auricularia auricula dregs obtained at different pyrolysis temperatures. The characterization of BC and batch experiment results showed that BC prepared at a higher temperature was more suitable for removing TC, where the maximum adsorption capacities of BC samples prepared at 300 °C, 500 °C, and 700 °C were 7.22 mg/g, 9.90 mg/g, and 11.90 mg/g, respectively. A pseudo-first order kinetics model and Freundlich, Temkin, and Dubinin-Radushkevich isotherm models fitted well to the adsorption data. Liquid film diffusion was the rate-controlling step. In addition, π-π electron donor-acceptor interactions may have played a dominant role in the adsorption mechanism between the enone structure of TC and aromatic C of BC. These results may facilitate further investigations of the adsorption mechanism and optimization of the process.