High strength, anti-freezing and strain sensing carboxymethyl cellulose-based organohydrogel

The gel-based sensor was extensively investigated due to the flexible and extensible properties. Here, a flexible, excellent mechanical (fracture energy of 5238 kJ/m³) and anti-freezing ionic conductive carboxymethyl cellulose-based organohydrogel sensor was prepared via Fe³⁺ cross-linked sodium carboxymethyl cellulose (CMC) as the first network and covalently cross-linked polyacrylamide as the second network in the co-solvents of water and ethylene glycol. Owing to the clipping transportation of Fe³⁺ in the water channels, the gel sensor had good sensitivity (GF = 1.4, 0˜30% strain) and fast strain-responsiveness (0.98 s) to monitor the subtle motions of human body. The CMC-based organohydrogel with high strain-sensitivity exhibited more potential applications of next-generation bioelectronic materials and devices.