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Updated: Jan 20, 2026

Low Pressure Vapor-assisted Solution Process for Tunable Band Gap Pinhole-free Methylammonium Lead Halide Perovskite Films
Published on: September 8, 2017
A polar-hydrophobic ionic liquid induces grain growth and stabilization in halide perovskites
Dan Liu1, Zhipeng Shao2, Jianzhou Gui3
1School of Chemistry and Chemical Engineering, Tianjin Polytechnic University, Tianjin 300387, P. R. China and School of Engineering, Brown University, Providence, Rhode Island 02912, USA. yuanyuan_zhou@brown.edu.
Abstract:
The addition of a polar-hydrophobic methylammonium trifluoroacetate ionic liquid tailors the hydrophobicity of halide-perovskite precursor solutions and assists in grain growth. This unique additive also functionalizes the grain boundaries via polar-polar interactions, thereby enhancing the optoelectronic properties and chemical stability of perovskites. This study opens the door to the solution hydrophobicity control towards high-performance perovskite devices.
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