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Updated: Jan 20, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
Published on: September 5, 2014
Hysteretic four-step spin-crossover in a 3D Hofmann-type metal-organic framework with aromatic guest
Cui-Juan Zhang1, Kai-Ting Lian1, Guo-Zhang Huang1
1Key Laboratory of Bioinorganic and Synthetic Chemistry of Ministry of Education, School of Chemistry, Sun Yat-Sen University, Guangzhou, 510275, P. R. China. nizhp@mail.sysu.edu.cn.
Abstract:
A new Hofmann-type metal-organic framework with bent pillar ligand, [Fe(dpoda){Ag(CN)2}2] (dpoda = 2,5-di-(pyridyl)-1,3,4-oxadiazole), was synthesized. Four-, two- and one-step spin-crossover (SCO) properties were obtained by using different sizes of aromatic guests. Most importantly, hysteretic four-step SCO behaviour with the sequence of LS ↔ HS0.25LS0.75↔ HS0.5LS0.5↔ HS0.67LS0.33↔ HS is observed for the first time.
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