Sb-Doped Titanium Oxide: A Rationale for Its Photocatalytic Activity for Environmental Remediation

The problem of water purification is one of the most urgent issues in developing countries, where large infrastructures and energy resources are limited. Among the possibilities for a cheap route to clean water, photocatalytic materials in the form of coatings or nanostructures are among the most promising. The most widely studied photocatalytic material is titanium dioxide (TiO₂). Here, we investigate the photocatalytic properties of 1.5% Sb-doped TiO₂ and laser-irradiated Sb-doped TiO . Calcined Sb-doped TiO₂ was found to adopt the rutile structure, but it turned amorphous after laser irradiation. Photocatalytic tests for Sb-doped TiO₂ showed an activity 1 order of magnitude higher than that of an undoped TiO₂ control sample under both ultraviolet and visible irradiation. A further sizeable enhancement resulted from laser irradiation. The increased photocatalytic activity is ascribed to both enhanced visible region absorption associated with Sb-induced lone pair surface electronic states and trapping of the holes at the lone pair surface sites, thus inhibiting the recombination of the electrons and holes generated in the initial photoexcitation step. This study shows the first rationalization of the photocatalytic properties of Sb-TiO₂ in terms of its electronic structure.