Palladium Supported on Porous Chitosan-Graphene Oxide Aerogels as Highly Efficient Catalysts for Hydrogen Generation...

Adsorption of Pd(NH₃)₄²⁺ in preformed chitosan-graphene oxide (CS-GO) beads and their subsequent reduction with NaBH₄ afford well-dispersed, high dispersion (~21%) of uniformly sized Pd nanoparticles (~1.7 nm). The resulting Pd/CS-GO exhibits interesting catalytic activity for hydrogen generation by ammonium formate decomposition. The optimal GO proportion of 7 wt% allows reaching, at 60 °C, a turnover frequency above 2200 h^-1-being outstanding among the highest values reported for this process to date. Interestingly, no formation of CO or CH₄ was detected. The catalyst did not leach, although it underwent gradual deactivation, probably caused by the increase in the Pd average size that became over 3 nm after three uses. Our results are relevant in the context of efficient on-board hydrogen generation from liquid organic hydrogen carriers in transportation.