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Updated: Jan 19, 2026

Heterogeneous Removal of Water-Soluble Ruthenium Olefin Metathesis Catalyst from Aqueous Media Via Host-Guest Interaction
Published on: August 23, 2018
Catalyst-Free Selective Oxidation of Diverse Olefins to Carbonyls in High Yield Enabled by Light under Mild
1State Key Laboratory of Fine Chemicals, School of Chemical Engineering , Dalian University of Technology , Dalian 116024 , P. R. China.
Abstract:
The selective oxidation of olefins, in particular, aromatic olefins to carbonyls, is of significance in organic synthesis. In general, stoichiometric toxic oxidants or a high-cost catalyst is required. Herein we report a novel and practical light-enabled protocol for the synthesis of carbonlys in high yield through a catalyst-free oxidation of olefins using H2O2 as a clean oxidant. A broad scope of carbonyls can be synthesized in high yield, and no catalyst or toxic oxidant is required.
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