Related Experiment Video
Updated: Jan 19, 2026
Combining Solid-state and Solution-based Techniques: Synthesis and Reactivity of ChalcogenidoplumbatesII or IV
Published on: December 29, 2016
Ternary Metal Chalcogenides: Into the Exciton and Biexciton Dynamics
Tushar Debnath1, Hirendra N Ghosh1,2
1Radiation and Photochemistry Division , Bhabha Atomic Research Centre , Mumbai 400085 , India.
Abstract:
Intra-band-gap state-induced low-toxicity colloidal I-III-VI ternary metal chalcogenide nanocrystals (NCs) have emerged as promising alternatives to the toxic Cd- and Pb-chalcogenides for different optoelectronic and bioimaging applications. In this Perspective, we provide the primary understanding of the intra-band-gap state-induced photoluminescence (PL) of I-III-VI NCs, specifically CuInS2 and AgInS2, as a function of particle size and composition and correlated with time-resolved PL measurements. The intra-band-gap state-induced ultrafast exciton and biexciton dynamics are discussed in detail to unravel the subpicosecond carrier relaxation dynamics through transient absorption measurement. Furthermore, ultrafast dissociation of the biexciton on Au@CuInS2 hybrid NCs has been revealed to be due to the presence of Au, which has direct relevance to the improvement of the solar cell efficiency. The proper fundamental insight of the ultrafast exciton and biexciton dynamics of these materials will enable utilization of ternary metal chalcogenides in photovoltaic as well as light-emitting devices.
More Related Videos
04:09Demonstrating the Simplicity and In Situ Temperature Monitoring of the Mechanochemical Synthesis of Metal Chalcogenides Suitable for Thermoelectrics
Published on: August 30, 2024
10:35Novel Techniques for Observing Structural Dynamics of Photoresponsive Liquid Crystals
Published on: May 29, 2018
Related Concept Videos
03:02Colors and Magnetism
When atoms or molecules absorb light at the proper frequency, their electrons are excited to higher-energy orbitals. For many main group atoms and molecules, the absorbed photons are in the ultraviolet range of the electromagnetic spectrum, which cannot be detected by the human eye. For coordination compounds, the energy difference between the d orbitals often allows photons in the visible range to be absorbed and emitted, which is seen as colors by the human...
02:46Crystal Field Theory - Tetrahedral and Square Planar Complexes
Crystal field theory (CFT) is applicable to molecules in geometries other than octahedral. In octahedral complexes, the lobes of the dx2−y2 and dz2 orbitals point directly at the ligands. For tetrahedral complexes, the d orbitals remain in place, but with only four ligands located between the axes. None of the orbitals points directly at the tetrahedral ligands. However, the dx2−y2 and dz2 orbitals (along the Cartesian axes) overlap with the ligands less than the dxy,...
02:42Valence Bond Theory
02:58Crystal Field Theory - Octahedral Complexes
To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
01:19Complexation Equilibria: The Chelate Effect
01:26Thermal and Photochemical Electrocyclic Reactions: Overview