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Crystal phase modulation of ZrO2 during the photothermal Sabatier reaction over Ni/ZrO2 catalysts
Zhouyan Zhao1, Xingyu Li1, Ying Dai1
1School of Chemistry and Materials Science, South-Central Minzu University, Wuhan 430074, China. li.wang@scuec.edu.cn.
Abstract:
Herein, a series of Ni/ZrO2 catalysts with tunable ZrO2 crystal phases were synthesized by controlling the calcination temperature of Ni/UiO-66(Zr). Ni/ZrO2-500 (t-ZrO2) exhibited higher activity than Ni/ZrO2-700 (m-ZrO2) in the photothermal Sabatier reaction, which was mainly attributed to a larger concentration of oxygen vacancies on the t-ZrO2 surface.
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