Wastewater from leather tanning and processing in Palestine: Characterization and management aspects

Leather manufacturing industry has major environmental impacts. Characterization of tannery's wastewater (WW) is a key step in the management of wastewater released from various processes. This study presents some physicochemical characteristics measured in wastewater. It compares the pollution loads released from both goat and cow hides processing. The main pollution characteristics of wastewater released from two local tanneries were determined experimentally, through analyzing real samples of industrial discharges. These include chemical oxygen demand (COD), total solids (TS), total dissolved solids (TDS), total suspended solids (TSS), pH, and the concentrations of chloride, ammonia (NH₃) and chromium in both states, Cr (III) and Cr (VI). Characterization of such processes effluents assists in identifying waste generation rates and discharges, and then in recommending cleaner production options. The results shows that the amount of WW produced in the local Palestinian tanneries is much lower than tanneries worldwide, whereas it is more concentrated with pollutants. Liming process has the highest COD and the highest pH value, where tanning process releases WW highly concentrated with chromium. Real process measurements and mass balance calculations indicated that the chromium uptake efficiency is only 46.6%. Such a low efficiency indicates that cleaner production measures are essential in local tanneries.