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Updated: Jan 18, 2026

Reverse Microemulsion-mediated Synthesis of Monometallic and Bimetallic Early Transition Metal Carbide and Nitride Nanoparticles
Published on: November 27, 2015
Tungsten-platinum μ-carbido and μ-methylidyne complexes
Benjamin J Frogley1, Anthony F Hill1
1Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory ACT 2601, Australia. a.hill@anu.edu.au.
Abstract:
Reactions of the lithiocarbyne [W][triple bond, length as m-dash]CLi ([W] = W(CO)2(Tp*); Tp* = tris(dimethylpyrazolyl)borate) with divalent platinum complexes [PtCl(terpy)]PF6, [PtCl2(η-C4R4)] (R = Me, Et), and [PtCl2(phen)] afford access to μ-carbido, μ-methylidyne and carbyne-based metallo-ligand complexes [Pt(C[triple bond, length as m-dash][W])(terpy)]PF6, [Pt(μ-HC[triple bond, length as m-dash][W])2] and [Pt(C[triple bond, length as m-dash][W])Cl(phen-C[triple bond, length as m-dash][W]-2)], respectively, the last of which provides a rare example of intermolecular organometallic nucleophilic attack at coordinated phenanthroline.
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