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Accurate Determination of the Equilibrium Surface Tension Values with Area Perturbation Tests
Published on: August 30, 2019
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A simple levitated-drop tensiometer
J Arcenegui-Troya1, A Belman-Martínez2, A A Castrejón-Pita1
1Department of Engineering Science, University of Oxford, Oxford OX1 3PJ, United Kingdom.
The Review of Scientific Instruments
|October 3, 2019
Summary
This paper introduces a novel, cost-effective liquid tensiometer that uses ultrasonic waves to levitate and vibrate tiny liquid samples. This method accurately measures surface tension using minimal sample volumes and allows for sample recovery.
Area of Science:
- Physical Chemistry
- Materials Science
- Analytical Chemistry
Background:
- Surface tension measurement is crucial for understanding liquid behavior and interfacial phenomena.
- Existing tensiometry methods can be complex, expensive, or require large sample volumes.
Purpose of the Study:
- To develop a reliable, simple, and affordable liquid tensiometer.
- To enable surface tension measurements with minimal sample volumes and rapid analysis.
Main Methods:
- Utilized a tractor beam configuration with 72 ultrasonic transmitters to levitate micro-liter liquid droplets.
- Induce controlled droplet vibrations via pressure instability for oscillation frequency detection.
- Employed a photodiode and oscilloscope to record droplet oscillation signals.
Main Results:
- Successfully measured effective surface tension by analyzing droplet oscillation frequencies.
- Demonstrated operation with millisecond timescale analysis (t < 12.5 ms) and minimal liquid volumes (∼0.5 μl).
- Validated the instrument's performance with diverse liquids including acetone, ethanol, Fluorinert FC-40, water, and whole milk.
Conclusions:
- The developed ultrasonic levitation tensiometer offers a reliable, simple, and affordable method for surface tension determination.
- The technique's low sample volume requirement and sample recoverability present significant advantages for various applications.

