Novel carbon and defects co-modified g-C₃N₄ for highly efficient photocatalytic degradation of bisphenol A under...

Graphite carbon nitride (g-C₃N₄, CN) is considered as a promising semiconductor for environmental catalysis. However, pure CN can not meet the requirements for actual applications due to its high recombination rate of photogenerated electron-hole pairs and a relatively large band gap preventing full utilization of solar energy. In this work, we report synthesis of a novel carbon and defects co-modified g-C₃N₄ (C_xCN) by calcination of melamine activated by oxalic. This new catalyst C_xCN has porous structure with much higher surface areas compared with pristine CN. UV-vis analysis and DFT calculations show that C_xCN has a lower bandgap for enhancing visible light adsorption compared with CN. Photoluminescence (PL) and photoelectrochemical analyses show that C_xCN has a low recombination rate of photogenerated electron-hole pairs, which improves the utilization of solar energy. As a result, C_xCN samples show high efficiency for the degradation of bisphenol A (BPA) under visible light irradiation, where the best catalyst of C_xCN (C_1.0CN) samples shows about 22 times higher photocatalytic degradation rate than that of CN. Moreover, C_1.0CN shows high mineralization rate and can degrade BPA into CO₂ and H₂O by the generated active species, like superoxide radicals (O₂^-) and holes (h⁺).