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[Au7Ag9(dppf)3(CF3CO2)7BF4]n: a linear nanocluster polymer from molecular Au7Ag8 clusters covalently linked by silver
Zhao-Rui Wen1, Zong-Jie Guan1, Ying Zhang1
1Department of Chemistry, College of Chemistry and Chemical Engineering Xiamen, 361005, P. R. China.
Chemical Communications (Cambridge, England)
|October 15, 2019
Abstract:
We report the total structure determination of a covalently bonded nanocluster polymer [Au7Ag9(dppf)3(CF3CO2)7BF4]n (1). This features a one-dimensional linear chain, consisting of unique molecular building blocks, Au7Ag8(dppf)3(CF3CO2)7 clusters, which are linked together by Ag-O bonds rather than Au-Au interactions or bidentate organic bridges as previously reported.
