Effective Synthesis of Carbon Hybrid Materials Containing Oligothiophene Dyes

This paper shows the first study of the synthesis of hybrid materials consisting of commercial Norit carbons and oligothiophenes. The study presents the influence of surface oxidation on dye deposition as well as changes of pore structure and surface chemistry. The hybrid materials were characterised using Raman spectroscopy, and scanning and transmission electron microscopy (SEM and HR-TEM, respectively). Confocal microscopy was employed to confirm the immobilization of oligomers on the surface of the carbons being investigated. Confocal microscopy measurements were additionally used to indicate whether dye molecules covered the entire surface of the selected commercial Norit samples. Specific surface area and pore structure parameters were determined by low-temperature nitrogen adsorption. Additionally, elemental content and surface chemistry were characterised by means of X-ray photoelectron spectroscopy (XPS) and combustion elemental analysis. Experimental results confirmed that oligothiophene dyes were adsorbed onto the internal part of the investigated pores of the carbon materials. The pores were assumed to have a slit-like shape, a set of 82 local adsorption isotherms was modelled for pores from 0.465 nm to 224 nm. Further, XPS data showed promising qualitative results regarding the surface characteristics and chemical composition of the hybrid materials obtained (sulphur content ranged from 1.40 to 1.45 at%). It was shown that the surface chemistry of activated carbon plays a key role in the dye deposition process. High surface heterogeneity after hydrothermal oxidation did not improve dye adsorption due to specific interactions between surface oxygen moieties and local electric charges in the oligothiophene molecules.