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A Technique to Functionalize and Self-assemble Macroscopic Nanoparticle-ligand Monolayer Films onto Template-free Substrates
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Self-assembled monolayers of polyoxovanadates with phthalocyaninato lanthanide moieties on gold surfaces
Ricarda Pütt1, Xinkai Qiu2, Piotr Kozłowski3
1Institut für Anorganische Chemie, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.
Chemical Communications (Cambridge, England)
|October 26, 2019
Abstract:
The two first representatives of phthalocyaninato (Pc) lanthanide-ligated polyoxovanadate cages {[V12O32(Cl)](LnPc)n}n-5 (n = 1 or 2, Ln = Yb3+) were synthesised and fully characterised. These magnetic complexes form two-dimensional self-assembled monolayers exhibiting electrical conductivity on gold substrate surfaces, as assessed by using an EGaIn tip.
