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Spatial Separation of Molecular Conformers and Clusters
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Protonated Clusters of Neon and Krypton
Michael Gatchell1,2, Paul Martini3, Arne Schiller3
1Institut für Ionenphysik und Angewandte Physik, Universität Innsbruck, Technikerstr. 25, A-6020, Innsbruck, Austria. michael.gatchell@uibk.ac.at.
Journal of the American Society for Mass Spectrometry
|October 26, 2019
Summary
Protonated and cationic clusters of neon and krypton were studied. Unlike argon and neon, cationic krypton clusters share magic numbers with protonated counterparts, indicating unique behavior in heavier rare gases.
Area of Science:
- Physical Chemistry
- Atomic and Molecular Physics
- Condensed Matter Physics
Background:
- Protonated rare gas clusters exhibit distinct magic sizes compared to cationic clusters, as observed in argon studies.
- Understanding cluster behavior is crucial for advancements in spectroscopy and materials science.
Purpose of the Study:
- To investigate the magic sizes of cationic and protonated neon and krypton clusters.
- To compare the behavior of neon and krypton clusters with previously studied argon clusters.
Main Methods:
- Experimental study of cationic and protonated neon and krypton clusters.
- Analysis of cluster properties to identify magic numbers.
Main Results:
- Neon clusters behave similarly to argon, showing differences between cationic and protonated magic sizes.
- Cationic krypton clusters exhibit greater similarity to protonated krypton clusters than lighter rare gases do.
- Shared magic numbers were identified between cationic and protonated krypton clusters.
Conclusions:
- Neon cluster behavior aligns with lighter rare gases, while krypton displays unique properties.
- The findings highlight the influence of atomic mass on rare gas cluster behavior and magic number characteristics.
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