Jove
Visualize
Contact Us
JoVE
x logofacebook logolinkedin logoyoutube logo
ABOUT JoVE
OverviewLeadershipBlogJoVE Help Center
AUTHORS
Publishing ProcessEditorial BoardScope & PoliciesPeer ReviewFAQSubmit
LIBRARIANS
TestimonialsSubscriptionsAccessResourcesLibrary Advisory BoardFAQ
RESEARCH
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchive
EDUCATION
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualFaculty Resource CenterFaculty Site
Terms & Conditions of Use
Privacy Policy
Policies

Related Concept Videos

You might also read

Related Articles

Articles linked to this work by shared authors, journal, and citation graph.

Sort by
Same author

A trifunctional cyclohexasilane for branched poly(cyclosilane)s.

Dalton transactions (Cambridge, England : 2003)·2026
Same author

Gel Metal-Organic Frameworks in Highly Concentrated Electrolyte Promote Stable Solid-Electrolyte Interface on Lithium Metal Anodes.

ACS applied materials & interfaces·2026
Same author

Low thermal inertia of carbonaceous asteroid Bennu driven by cracks observed in returned samples.

Nature communications·2026
Same author

Pore Choices: The Delicate Balance of Porosity and External Surface Area in Zirconium Metal-Organic Frameworks for Lithium-Sulfur Batteries.

ACS applied materials & interfaces·2025
Same author

1,2-Migratory ring expansion of a BN-naphthalene.

Organic & biomolecular chemistry·2025
Same author

Electronic Modification of a Reduced Mononuclear Nonheme Iron Nitrosyl Complex Leads to HNO Release.

Journal of the American Chemical Society·2025

Related Experiment Video

Updated: Jan 4, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

49.0K

2D Oligosilyl Metal-Organic Frameworks as Multi-state Switchable Materials.

David A Burns1, Eric M Press1, M A Siegler1

  • 1Department of Chemistry, Johns Hopkins University, 3400 N Charles Street, Baltimore, MD, 21218, USA.

Angewandte Chemie (International Ed. in English)
|October 31, 2019
PubMed
Summary

Researchers synthesized novel 2D metal-organic frameworks (MOFs) using silicon-based linkers. These unique oligosilyl MOFs exhibit tunable structures and reversible phase transformations, opening new avenues in materials science.

Keywords:
2D materialsmetal-organic frameworks (MOFs)phase changessilanesstructural interconversion

More Related Videos

Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
04:51

Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange

Published on: June 23, 2023

4.0K
Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

16.5K

Related Experiment Videos

Last Updated: Jan 4, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
11:27

Synthesis and Characterization of Functionalized Metal-organic Frameworks

Published on: September 5, 2014

49.0K
Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange
04:51

Author Spotlight: Functionalizing Metal-Organic Frameworks: Advancements, Challenges, and the Power of Post-Synthetic Ligand Exchange

Published on: June 23, 2023

4.0K
Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance
08:12

Surface Functionalization of Metal-Organic Frameworks for Improved Moisture Resistance

Published on: September 5, 2018

16.5K

Area of Science:

  • Materials Science
  • Inorganic Chemistry
  • Nanotechnology

Background:

  • Metal-organic frameworks (MOFs) are crystalline materials with tunable porous structures.
  • Organosilicon compounds offer unique properties for materials synthesis.

Purpose of the Study:

  • To synthesize novel 2D metal-organic frameworks (MOFs) utilizing organosilicon-based linkers.
  • To investigate the structural properties and phase transformation behaviors of these new MOFs.

Main Methods:

  • Synthesis of 2D MOFs using linear oligosilyl ligands (lin-Si n, n=2, 4) and copper paddlewheel nodes.
  • Characterization of framework structures and investigation of structural transformations via solvent exchange.

Main Results:

  • Successful synthesis of 2D oligosilyl MOFs with linear Si nMe 2n(C 6 H 4 CO 2 H) 2 ligands.
  • Demonstration of tunable stacking arrangements governed by van der Waals interactions.
  • Observation of reversible structural transformations between crystalline and amorphous phases.

Conclusions:

  • Organosilicon linkers can be effectively employed in the construction of 2D MOFs.
  • The van der Waals interactions in these MOFs allow for tunable structures and reversible phase changes.
  • These findings expand the scope of MOF chemistry and offer potential for responsive materials.